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*Apr 08, 2013 The ∆H for the solution process when solid sodium hydroxide dissolves in water is 44.4 kJ/mol. The ∆H for the solution process when solid sodium hydroxide dissolves in water is 44.4.
*The NaOH module calculates the physical properties of aqueous sodium hydroxide solutions in the temperature range from 20 °C to 100 °C and in the concentration range from 0 to 50 Ma-% NaOH. The following physical properties are calculated: Density; Specific heat capacity; Thermal conductivity; Dynamic viscosity; Kinematic viscosity; Prandtl.
Sodium hydroxide is used to manufacture many everyday products, such as paper, aluminum, commercial drain and oven cleaners, and soap and detergents. Sodium Hydroxide in Cleaning & Disinfectant Products. Sodium hydroxide is used to manufacture soaps and a variety of detergents used in homes and commercial applications. See full list on webbook.nist.gov. The NaOH module calculates the physical properties of aqueous sodium hydroxide solutions in the temperature range from 20 °C to 100 °C and in the concentration range from 0 to 50 Ma-% NaOH. The following physical properties are calculated: Density; Specific heat capacity; Thermal conductivity; Dynamic viscosity; Kinematic viscosity; Prandtl. Specific heat for some common liquids and fluids - acetone, oil, paraffin, water and many more
The specific heat for some commonly used liquids and fluids is given in the table below.
For conversion of units, use the Specific heat online unit converter.
See also tabulated values of specific heat of gases, food and foodstuff, metals and semimetals, common solids and other common substances as well as values of molar specific heat of common organic substances and inorganic substances.ProductSpecific Heat
- cp -
(kJ/(kg K))(Btu/(lb oF))
(Kcal/kg oC)Acetic acid2.0430.49Acetone2.150.51Alcohol, ethyl 32oF (ethanol)2.30.548Alcohol, ethyl 104oF (ethanol)2.720.65Alcohol, methyl. 40 - 50oF2.470.59Alcohol, methyl. 60 - 70oF2.510.6Alcohol, propyl2.370.57Ammonia, 32oF4.61.1Ammonia, 104oF4.861.16Ammonia, 176oF5.41.29Ammonia, 212oF6.21.48Ammonia, 238oF6.741.61Aniline2.180.514Benzene, 60oF1.80.43Benzene, 150oF1.920.46Benzine2.1Benzol1.80.43Bismuth, 800oF0.150.0345Bismuth, 1000oF0.1550.0369Bismuth, 1400oF0.1650.0393Bromine0.470.11n-Butane, 32oF2.30.55Calcium Chloride3.060.73Carbon Disulfide0.9920.237Carbon Tetrachloride0.8660.207Castor Oil1.80.43Chloroform1.050.251Citron Oil1.840.44Decane2.210.528Diphenylamine1.930.46Dodecane2.210.528Dowtherm1.550.37Ether2.210.528Ethyl ether2.220.529Ethylene glycol2.360.56Dichlorodifluoromethane R-12 saturated -40oF0.880.211Dichlorodifluoromethane R-12 saturated 0oF0.910.217Dichlorodifluoromethane R-12 saturated 120oF1.020.244Fuel Oil min.1.670.4Fuel Oil max.2.090.5Gasoline2.220.53Glycerine2.430.576Heptane2.240.535Hexane2.260.54Hydrochlor acid3.14Iodine2.150.51Kerosene2.010.48Linseed Oil1.840.44Light Oil, 60oF1.80.43Light Oil, 300oF2.30.54Mercury0.140.03Methyl alcohol2.51Milk3.930.94Naphthalene1.720.41Nitric acid1.72Nitro benzole1.520.362Octane2.150.51Oil, Castor1.970.47Oil, Olive1.970.47Oil, mineral1.670.4Oil, turpentine1.8Oil, vegetable1.670.4Olive oil1.970.47Paraffin2.130.51Perchlor ethylene0.905Petroleum2.130.51Petroleum ether1.76Phenol1.430.34Potassium hydrate3.680.88Propane, 32oF2.40.576Propylene2.850.68Propylene Glycol2.50.60Sesame oil1.630.39Sodium, 200oF1.380.33Sodium, 1000oF1.260.3Sodium hydrate3.930.94Soya bean oil1.970.47Sulfuric acid concentrated1.38Sulfuric acid1.34Toluene1.720.41Trichlor ethylene1.30Tuluol1.510.36Turpentine1.720.411Water, fresh4.191Water, sea 36oF3.930.938Xylene1.720.41
*1 kJ/(kg K) = 1000 J/(kgoC) = 0.2389 kcal/(kg oC) = 0.2389 Btu/(lbmoF)
*T(oC) = 5/9[T(oF) - 32]
For conversion of units, use the Specific heat online unit converter.
See also tabulated values of specific heat of Gases, Food and foodstuff, Metals and semimetals, Common solids and other Common substances.Heating Energy
The energy required to heat a product can be calculated as
q = cp m dt (1)

where
q = heat required (kJ)
cp = specific heat (kJ/kg K, kJ/kg oC)
dt = temperature difference (K, oC)Example - Required Heat to increase Temperature i Water
10 kg of water is heated from 20 oC to 100 oC - a temperature difference 80 oC (K). The heat required can be calculated as
q = (4.19 kJ/kg K) (10 kg) (80 oC)
= 3352 kJ Related Topics
* Material Properties - Material properties for gases, fluids and solids - densities, specific heats, viscosities and more
* Thermodynamics - Effects of work, heat and energy on systems Related Documents
* Ammonia - Density at Varying Temperature and Pressure - Online calculator, figures and tables showing density and specific weight of ammonia at temperatures ranging -50 to 425 °C (-50 to 800 °F) at atmospheric and higher pressure - Imperial and SI Units
* Ammonia - Dynamic and Kinematic Viscosity - Online calculator, figures and tables showing dynamic (absolute) and kinematic viscosity of gasous and liquid ammonia at temperatures ranging from -73 to 425°C (-100 to 800°F) at pressure ranging from 1 to 1000 bara (14.5 - 14500 psia) - SI and Imperial Units
* Ammonia - Properties at Gas-Liquid Equilibrium Conditions - Figures and tables showing how the properties of liquid and gaseous ammonia changes along the boiling/condensation curve (temperature and pressure between triple point and critical point conditions). An ammonia phase diagram are included.
* Ammonia - Specific Heat at varying Temperature and Pressure - Online calculator, figures and tables showing specific heat, CP and CV, of gasous and liquid ammonia at temperatures ranging from -73 to 425°C (-100 to 800°F) at pressure ranging from 1 to 100 bara (14.5 - 1450 psia) - SI and Imperial Units
* Ammonia - Thermal Conductivity at Varying Temperature and Pressure - Online calculator, figures and tables showing thermal conductivity of liquid and gaseous ammonia at temperatures ranging -70 to 425 °C (-100 to 800 °F) at atmospheric and higher pressure - Imperial and SI Units
* Ammonia - Thermophysical Properties - Chemical, Physical and Thermal Properties of Ammonia. Phase diagram included.
* Ammonia - Vapour Pressure at gas-liquid equilibrium - Figures and table showing ammonia saturation pressure at boiling point, SI and Imperial units
* Electric Heating of a Mass - Electric heating of an object or mass - energy supply and temperature change
* Heat Capacity - The heat capacity of a substance is the amount of heat required to change its temperature by one degree, and has units of energy per degree
* Heat Emission from Pipes Submerged in Oil or Fat - Heat emission from steam or water heating pipes submerged in oil or fat - forced and natural circulation
* Heat Up Applications - Energy Required and Heat Transfer Rates - Energy required to heat up a substance
* Light Oil Suction Flow Velocity - Recommended suction flow velocity when pumping light oils
* Liquid ammonia - Thermal Properties at saturation pressure - Density, specific heat, thermal conductivity, viscosity and Prandtls no. of liquid ammonia at its saturation pressure
* Mixing Fluids - Final mass and temperature when mixing fluids
* Mixing Liquids and/or Solids - Final Temperatures - Calculate the final temperature when liquids or solids are mixed
* Oil Tanks Heat Loss - Heat loss from lagged and unlagged, sheltered and exposed oil tanks
* Polymers - Specific Heats - Specific heat of polymers like epoxy, PET, polycarbonate and more
* Specific Heat - Online Unit Converter - Online specific heat converter with the most commonly used units
* Specific Heat and Individual Gas Constants of Gases - Specific heat at constant volume, specific heat at constant pressure, specific heat ratio and individual gas constant - R - common gases as argon, air, ether, nitrogen and many more .
* Specific Heat of Food and Foodstuff - Specific heat of common food and foodstuff like apples, bass, beef, pork and many more
* Specific Heat of Solids - Common solids - like brick, cement, glass and many more - and their specific heats - in Imperial and SI units
* Steel Pipes and Temperature Expansion - Temperature expansion of carbon steel pipes
* Storing Thermal Heat in Materials - Energy stored as sensible heat in materials
* Sulfuric Acid - Density - Density of sulfuric acid at various temperatures and concentrations
* Water - Specific Heat - Online calculator, figures and tables showing specific heat of liquid water at constant volume or constant pressure at temperatures from 0 to 360 °C (32-700 °F) - SI and Imperial units Tag Search
*en: specific heat capacity fluids liquids
*es: fluidos capacidad calorífica líquidos específicos
*de: spezifische Wärmekapazität Flüssigkeiten Flüssigkeiten
*Formula: HNaO
*Molecular weight: 39.9971
*IUPAC Standard InChI:

*InChI=1S/Na.H2O/h;1H2/q+1;/p-1
*Download the identifier in a file.
*IUPAC Standard InChIKey:HEMHJVSKTPXQMS-UHFFFAOYSA-M
*CAS Registry Number: 1310-73-2
*Chemical structure:
This structure is also available as a 2d Mol fileor as a computed3d SD file
The 3d structure may be viewed usingJavaorJavascript.
*Species with the same structure:
*Information on this page:
*Data at other public NIST sites:
*Options:Data at NIST subscription sites:
NIST subscription sites provide data under theNIST Standard ReferenceData Program, but require an annual fee to access.The purpose of the fee is to recover costs associatedwith the development of data collections included insuch sites. Your institution may already be a subscriber.Follow the links above to find out more about the datain these sites and their terms of usage.Gas phase thermochemistry data
Go To:Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
QuantityValueUnitsMethodReferenceCommentΔfH°gas-197.76kJ/molReviewChase, 1998Data last reviewed in December, 1970QuantityValueUnitsMethodReferenceCommentS°gas,1 bar228.47J/mol*KReviewChase, 1998Data last reviewed in December, 1970Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.

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View table.Temperature (K)2500. - 6000.A49.46492B7.000125C-1.391757D0.095206E-0.256928F-213.6706G284.8609H-197.7572ReferenceChase, 1998CommentData last reviewed in December, 1970Condensed phase thermochemistry data
Go To:Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.Specific Heat Capacity Of WaterQuantityValueUnitsMethodReferenceCommentΔfH°liquid-416.88kJ/molReviewChase, 1998Data last reviewed in December, 1970QuantityValueUnitsMethodReferenceCommentS°liquid,1 bar75.91J/mol*KReviewChase, 1998Data last reviewed in December, 1970QuantityValueUnitsMethodReferenceCommentΔfH°solid-425.93kJ/molReviewChase, 1998Data last reviewed in December, 1970QuantityValueUnitsMethodReferenceCommentS°solid64.46J/mol*KReviewChase, 1998Data last reviewed in December, 1970Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.

View plotRequires a JavaScript / HTML 5 canvas capable browser.
View table.Temperature (K)596. - 2500.A88.34725B-2.495103C-3.013028D0.862607E0.042216F-442.9350G183.9320H-416.8783ReferenceChase, 1998CommentData last reviewed in December, 1970Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.

View plotRequires a JavaScript / HTML 5 canvas capable browser.
View table.Temperature (K)298. - 572.572. - 596.A419.483786.02304B-1717.7540.000000C2953.5730.000000D-1597.2210.000000E-6.0468840.000000F-517.8662-448.8512G933.0738169.6281H-425.9312-425.9312ReferenceChase, 1998Chase, 1998CommentData last reviewed in December, 1970Data last reviewed in December, 1970Reaction thermochemistry data
Go To:Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below. Individual Reactions
2 + = + +
By formula: 2HNaO + C2H3FO = C2H3NaO2 + FNa + H2OSodium Hydroxide Solution Specific Heat CapacityQuantityValueUnitsMethodReferenceCommentΔrH°-56.15 ± 0.08kJ/molCmPritchard and Skinner, 1950liquid phase; Corrected for CODATA value of ΔfH; HF(100); ALSΔrH°-177.kJ/molCmCarson and Skinner, 1949liquid phase; ALS
2 + = + 2 + 2
By formula: 2HNaO + C2H6O4 = H2 + 2CHNaO2 + 2H2OQuantityValueUnitsMethodReferenceCommentΔrH°-293.3 ± 5.0kJ/molCmJenkins and Style, 1953solid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -292. kJ/mol; ALS
+ = Hazards Of Sodium Hydroxide
By formula: HNaO + C2H2O = C2H3NaO2QuantityValueUnitsMethodReferenceCommentΔrH°-208.2 ± 1.6kJ/molCmNuttall, Laufer, et al., 1971gas phase; ALSΔrH°-197.3kJ/molCmRice and Greenberg, 1934gas phase; ALS
C2Na2 (cr) + 2 (l) = 2( • 1418) (solution) + (g)
By formula: C2Na2 (cr) + 2H2O (l) = 2(HNaO • 1418H2O) (solution) + C2H2 (g)QuantityValueUnitsMethodReferenceCommentΔrH°-161.8 ± 1.5kJ/molRSCJohnson, van Deventer, et al., 1973Please also see Pedley and Rylance, 1977.; MS
C2HNa (cr) + (l) = ( • 1418) (solution) + (g)
By formula: C2HNa (cr) + H2O (l) = (HNaO • 1418H2O) (solution) + C2H2 (g)QuantityValueUnitsMethodReferenceCommentΔrH°-54.2 ± 0.8kJ/molRSCJohnson, van Deventer, et al., 1973Please also see Pedley and Rylance, 1977.; MS
3 + = CNa2O3 + + +
By formula: 3HNaO + C3H5ClO2 = CNa2O3 + C2H6O + ClNa + H2OQuantityValueUnitsMethodReferenceCommentΔrH°-323.3 ± 1.7kJ/molCmDavies, Finch, et al., 1980liquid phase; Heat of hydrolysis; ALS
2 + = + + CNO.Na
By formula: 2HNaO + CBrN = BrNa + H2O + CNO.NaQuantityValueUnitsMethodReferenceCommentΔrH°-234.6 ± 0.71kJ/molCmLord and Woolf, 1954solid phase; Heat of hydrolysis; ALS
2 + = + + CNO.Na
By formula: 2HNaO + CIN = INa + H2O + CNO.NaQuantityValueUnitsMethodReferenceCommentΔrH°-193.9 ± 0.3kJ/molCmLord and Woolf, 1954solid phase; Heat of hydrolysis; ALS
2 + = + + CNO.Na
By formula: 2HNaO + CClN = ClNa + H2O + CNO.NaQuantityValueUnitsMethodReferenceCommentΔrH°-277.5 ± 0.4kJ/molCmLord and Woolf, 1954solid phase; Heat of Hydrolysis; ALS
+ = +
By formula: C2HBr3O + HNaO = CHNaO2 + CHBr3QuantityValueUnitsMethodReferenceCommentΔrH°-93.72kJ/molCmPritchard and Skinner, 1950, 2liquid phase; Heat of hydrolysis; ALS
+ = +
By formula: HNaO + C2HCl3O = CHNaO2 + CHCl3QuantityValueUnitsMethodReferenceCommentΔrH°-102.8kJ/molCmPritchard and Skinner, 1950, 2liquid phase; Heat of hydrolysis; ALS
+ = +
By formula: HNaO + C2H5NO = C2H3NaO2 + H3NQuantityValueUnitsMethodReferenceCommentΔrH°-45.6kJ/molCmCalvet, 1933solid phase; Heat of hydrolysis; ALS
C6H5NaO (cr) + (l) = (cr) + (cr)
By formula: C6H5NaO (cr) + H2O (l) = C6H6O (cr) + HNaO (cr)QuantityValueUnitsMethodReferenceCommentΔrH°21.4 ± 3.6kJ/molRSCLeal, Pires de Matos, et al., 1991MSSodium Hydroxide Specific Heat Capacity Formula
C2H5NaO (cr) + (l) = (cr) + (l)
By formula: C2H5NaO (cr) + H2O (l) = HNaO (cr) + C2H6O (l)QuantityValueUnitsMethodReferenceCommentΔrH°-5.7 ± 1.9kJ/molRSCLeal, Pires de Matos, et al., 1991MS
(cr) + (l) = (cr) + (l)
By formula: CH3NaO (cr) + H2O (l) = HNaO (cr) + CH4O (l)QuantityValueUnitsMethodReferenceCommentΔrH°-6.5 ± 2.4kJ/molRSCLeal, Pires de Matos, et al., 1991MSGas phase ion energetics data
Go To:Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Data evaluated by:Edward P. Hunter and Sharon G. LiasQuantityValueUnitsMethodReferenceCommentProton affinity (review)1071.8kJ/molN/AHunter and Lias, 1998QuantityValueUnitsMethodReferenceCommentGas basicity1044.8kJ/molN/AHunter and Lias, 1998References
Go To:Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved.
Chase, 1998
Chase, M.W., Jr.,NIST-JANAF Themochemical Tables, Fourth Edition,J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A.,The heat of hydrolysis of acetyl fluoride,J. Chem. Soc., 1950, 1099. [all data]
Carson and Skinner, 1949
Carson, A.S.; Skinner, H.A.,201. Carbon-halogen bond energies in the acetyl halides,J. Chem. Soc., 1949, 936-939. [all data]
Jenkins and Style, 1953
Jenkins, A.D.; Style, D.W.G.,The thermochemistry and pyrolysis of bishydroxymethyl,J. Chem. Soc., 1953, 2337-23. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]Sodium Hydroxide Heat Of Dilution
Nuttall, Laufer, et al., 1971
Nuttall, R.L.; Laufer, A.H.; Kilday, M.V.,The enthalpy of formation of ketene,J. Chem. Thermodyn., 1971, 3, 167-174. [all data]
Rice and Greenberg, 1934
Rice, F.O.; Greenberg, J.,Ketene. III. Heat of formation and heat of reaction with alcohols,J. Am. Chem. Soc., 1934, 38, 2268-2270. [all data]
Johnson, van Deventer, et al., 1973
Johnson, G.K.; van Deventer, E.H.; Ackerman, J.P.; Hubbard, W.N.; Osborne, D.W.; Flotow, H.L.,J. Chem. Thermodyn., 1973, 5, 57. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Davies, Finch, et al., 1980
Davies, R.H.; Finch, A.; Gardner, P.J.,The

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